Pentachlorophenol → HCID 86733441, compound

HRID 2419175Notes

Reaction equation

HRID 2419175 reaction equation
[Cl:1][C:2]1[C:7]([OH:8])=[C:6]([Cl:9])[C:5]([Cl:10])=[C:4]([Cl:11])[C:3]=1[Cl:12].[Al].[OH:14][CH2:15][C:16]([CH2:21][OH:22])([CH2:19][OH:20])[CH2:17][OH:18].[CH2:23]([O:25][P:26]([O:30][CH2:31][CH3:32])[O:27][CH2:28][CH3:29])[CH3:24]>[Fe]>[Cl:1][C:2]1[C:7]([OH:8])=[C:6]([Cl:9])[C:5]([Cl:10])=[C:4]([Cl:11])[C:3]=1[Cl:12].[OH:14][CH2:15][C:16]([CH2:21][OH:22])([CH2:19][OH:20])[CH2:17][OH:18].[CH2:23]([O:25][P:26]([O:30][CH2:31][CH3:32])[O:27][CH2:28][CH3:29])[CH3:24].[CH2:6]1[O:8][CH:7]1[CH3:2]

Participants

6

Reactant 4

HCID 992PentachlorophenolHCID 8285PentaerythritolHCID 31215Triethyl phosphiteHCID 5359268Aluminum

Product 1

HCID 86733441HCID 86733441, compound

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

A 5-liter flask was charged with 1330 grams of pentachlorophenol, containing about 750 ppm of aluminum and iron compounds, 680 grams of pentaerythritol and 290 grams of triethylphosphite. The mixture was stirred and heated and volatiles were removed until the temperature was 145° C. Propylene oxide was then added until the acid number was less than 1. Since some solid materials was present 253 grams of pentachlorophenol was added and propylene oxide addition was continued until the acid number was less than 1. The mixture was stripped to remove volatiles and filtered through a coarse paper. The resulting oxypropylated polyol product weighted 3398 grams and had the following properties:

Workup

  1. temperatureheated
  2. customvolatiles were removed until the temperature
  3. customwas 145° C
  4. additionPropylene oxide was then added until the acid number
  5. additionwas added
  6. additionpropylene oxide addition
  7. customto remove volatiles
  8. filtrationfiltered through a coarse paper

Sources & evidence

ORD record
ord-4444fcc0a82f42baa7db382fa3d72b83
Source dataset
uspto-grants-1978_08
Patent number
US04105597

Reaction notes

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