Hydrogen Peroxide → HCID 20306117, compound

HRID 2419328Notes

Reaction equation

HRID 2419328 reaction equation
[N+]([O-])(O)=O.[CH3:5][S:6][C:7]1[CH:12]=[CH:11][C:10]([CH:13]([CH2:20][CH2:21][CH2:22][CH3:23])[CH2:14][N:15]2[CH:19]=[CH:18][N:17]=[CH:16]2)=[CH:9][CH:8]=1.OO.[OH2:26].[OH-:27].[Na+]>C(O)(=O)C>[CH3:5][S:6]([C:7]1[CH:8]=[CH:9][C:10]([CH:13]([CH2:20][CH2:21][CH2:22][CH3:23])[CH2:14][N:15]2[CH:19]=[CH:18][N:17]=[CH:16]2)=[CH:11][CH:12]=1)(=[O:27])=[O:26]

Participants

6

Reactant 4

HCID 784Hydrogen PeroxideHCID 962WaterHCID 14798Sodium HydroxideHCID 20306129Nitric acid--1-{2-[4-(methylsulfanyl)phenyl]hexyl}-1H-imidazole (1/1)

Product 1

HCID 20306117HCID 20306117, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

To 7.0g (0.021 mole) of 1-[β-(p-methylthiophenyl)hexyl]imidazole nitric acid salt in 75 ml of glacial acetic acid is added dropwise at less than 10°, 8.0g (0.083 mole) of 35% hydrogen peroxide. When the addition is complete, the reaction is stirred for one hour heated on a steambath for a second hour and then poured into iced water. The solution is made basic to litmus with sodium hydroxide and the product is extracted out with ether.

Workup

  1. additionWhen the addition
  2. temperatureheated on a steambath for a second hour
  3. extractionthe product is extracted out with ether

Sources & evidence

ORD record
ord-e5497f96730c4bf1a150289c383888ee
Source dataset
uspto-grants-1978_08
Patent number
US04105762

Reaction notes

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