HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromine → Isopropyl 4-(bromoacetyl)phenoxyacetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromine | HCID 24408 | — |
| Reactant | HCID 20315614 | HCID 20315614 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | Isopropyl 4-(bromoacetyl)phenoxyacetate | HCID 20315599 | — |
Reaction Steps
Bromine (12g.) was added dropwise to a stirred solution of isopropyl 4-acetylphenoxyacetate (17.6g.) in benzene (200ml.) over 30 minutes. The solution was stirred for a further 15 minutes and then evaporated. The residue was crystallised from ether/hexane to give isopropyl 4-(bromoacetyl)phenoxyacetate, m.p. 60°-61° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04105790 |
| Source dataset | uspto-grants-1978_08 |
| ORD ID | ord-75ec40ed7bc648b49419d273f9ac3f8a |
| Source note | uspto-grants-1978_08 |