4'-Hydroxyacetophenone → HCID 20315551, compound

HRID 2419361Notes

Reaction equation

Br[CH:2]([C:8]([O:10][CH2:11][CH3:12])=[O:9])[C:3]([O:5][CH2:6][CH3:7])=[O:4].[CH3:13][C:14]([C:16]1[CH:17]=[CH:18][C:19]([OH:22])=[CH:20][CH:21]=1)=[O:15]>>[C:14]([C:16]1[CH:21]=[CH:20][C:19]([O:22][CH:2]([C:8]([O:10][CH2:11][CH3:12])=[O:9])[C:3]([O:5][CH2:6][CH3:7])=[O:4])=[CH:18][CH:17]=1)(=[O:15])[CH3:13]

Participants

Reactant 2

HCID 74694'-Hydroxyacetophenone

HCID 69637Diethyl bromomalonate

Product 1

HCID 20315551HCID 20315551, compound

Procedure

Diethyl bromomalonate was reacted with 4-hydroxyacetophenone to give diethyl 4-acetylphenoxymalonate by the procedure described for the preparation of isopropyl 4-acetylphenoxyacetate.

Sources & evidence

ORD record: ord-608e3d8b873e45c580be167609447b20
Source dataset: uspto-grants-1978_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04105790

Reaction notes

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