Sodium Iodide → HCID 14662926, compound

HRID 2419630Notes

Reaction equation

HRID 2419630 reaction equation
[CH3:1][O:2][CH:3]([O:10][CH3:11])[C:4](=[O:9])/[CH:5]=[CH:6]\[CH2:7][CH3:8].[I-].[Na+]>C(O)(=O)C>[CH3:11][O:10][CH:3]([O:2][CH3:1])[C:4](=[O:9])/[CH:5]=[CH:6]/[CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 57417966HCID 57417966, compound2×

Product 1

HCID 14662926HCID 14662926, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

The crude product produced in Example III is dissolved in 6 ml of acetic acid with 0.1 g of sodium iodide. By GLC analysis on Carbowax (polyethylene glycol) it is clear that the 1,1-dimethoxy-cis-3-hexene-2-one is converted to a new material of later retention time. After one-half hour, less than 5% of "cis" material remains.

Workup

  1. waitAfter one-half hour

Sources & evidence

ORD record
ord-e9de3368aa5b4f8f98f4da9047ffdf1c
Source dataset
uspto-grants-1978_08
Patent number
US04107217

Reaction notes

Loading…