Hydrogen Peroxide → HCID 23339643, compound

HRID 2419849Notes

Reaction equation

HRID 2419849 reaction equation
[F:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH2:9][CH2:10][CH2:11][C:12]([NH:14][OH:15])=[O:13])=[CH:4][CH:3]=1.[OH:16]O>C(O)(=O)C>[F:1][C:2]1[CH:3]=[CH:4][C:5]([S:8]([CH2:9][CH2:10][CH2:11][C:12]([NH:14][OH:15])=[O:13])=[O:16])=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 20314603HCID 20314603, compound

Product 1

HCID 23339643HCID 23339643, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

10.5 g (0.046 mol) of 4-(p-fluorophenylthio)-butyrohydroxamic acid dissolved in 45 ml of acetic acid are oxidised with 4.6 ml of hydrogen peroxide of 110 volumes strength. After 1 hour at 50° C, the mixture is left to stand overnight and is then evaporated to dryness in vacuo. The residue is taken up in ethyl acetate and filtered off.

Workup

  1. waitthe mixture is left
  2. waitto stand overnight
  3. customis then evaporated to dryness in vacuo
  4. filtrationfiltered off

Sources & evidence

ORD record
ord-3395e24959e84c4596c0f30a69b9fdca
Source dataset
uspto-grants-1978_08
Patent number
US04107438

Reaction notes

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