Hydrogen Peroxide → HCID 23339631, compound

HRID 2419851Notes

Reaction equation

HRID 2419851 reaction equation
[F:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH2:9][CH2:10][C:11]([NH:13][OH:14])=[O:12])=[CH:4][CH:3]=1.[OH:15]O>C(O)(=O)C>[F:1][C:2]1[CH:3]=[CH:4][C:5]([S:8]([CH2:9][CH2:10][C:11]([NH:13][OH:14])=[O:12])=[O:15])=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 20314601HCID 20314601, compound

Product 1

HCID 23339631HCID 23339631, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

9.85 g (0.046 mol) of 3-(p-fluorophenylthio)-propiohydroxamic acid dissolved in 46 ml of acetic acid are oxidised by adding 4.6 ml of hydrogen peroxide of 110 volumes strength. The reactants are left in contact for 3 hours, the mixture is evaporated to dryness in vacuo, the residue is taken up in ethyl acetate and the product is filtered off and recrystallised from ethanol.

Workup

  1. customthe mixture is evaporated to dryness in vacuo
  2. filtrationthe product is filtered off
  3. customrecrystallised from ethanol

Sources & evidence

ORD record
ord-fd8adeddaf61431588f2156917a27e59
Source dataset
uspto-grants-1978_08
Patent number
US04107438

Reaction notes

Loading…