HCID 594380, compound → HCID 2834903, compound

HRID 2419982Notes

Reaction equation

HRID 2419982 reaction equation
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH:6]1[C:19]2[C:10](=[NH+:11][CH:12]=[C:13]3[C:18]=2[CH:17]=[CH:16][CH:15]=[CH:14]3)[CH:9]=[CH:8][CH:7]=1.[C:20]1([C:26]([CH3:31])=[CH:27][C:28](=O)[CH3:29])[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1>CO>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:29][C:28]1[N+:11]2[C:10]3[CH:9]=[CH:8][CH:7]=[CH:6][C:19]=3[C:18]3[C:13]([C:12]=2[CH:31]=[C:26]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:27]=1)=[CH:14][CH:15]=[CH:16][CH:17]=3

Participants

4

Reactant 2

HCID 594380HCID 594380, compoundHCID 20312263HCID 20312263, compound

Product 1

HCID 2834903HCID 2834903, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Phenanthridinium perchlorate (2 g) and 4-phenylpent-3-ene-2-one (4 g) were heated together at 150° for 16 hours. The reaction mixture was cooled and diluted with methanol. The product was isolated by filtration and recrystallized from acetonitrile. Yield 1.5 g, m.p. 252°-3°.

Workup

  1. temperatureThe reaction mixture was cooled
  2. customThe product was isolated by filtration
  3. customrecrystallized from acetonitrile

Sources & evidence

ORD record
ord-9e579a6f58994ed590822f029d6032e2
Source dataset
uspto-grants-1978_08
Patent number
US04108667

Reaction notes

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