HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Chloroethanol → 2,6-Di-tert-butyl-4-[(2-hydroxyethyl)sulfanyl]phenol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Chloroethanol | HCID 34 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | 2,6-Di-tert-butyl-4-mercaptophenol | HCID 70370 | — |
| Solvent | Benzene | HCID 241 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 2,6-Di-tert-butyl-4-[(2-hydroxyethyl)sulfanyl]phenol | HCID 14011815 | — |
Reaction Steps
Using the equipment described in Example I, 2,6-ditertiary butyl-4-mercaptophenol (50 grams) was dissolved in 90 millimeters of ethanol (denatured alcohol) and 30 millimeters of benzene. A solution of 12 grams of KOH in 60 millimeters of ethanol was added under a nitrogen blanket. 2-Chloroethanol (19 grams) was slowly added dropwise at room temperature. The combination was reacted for three hours and then diluted with benzene and washed with water. The volatiles were then stripped off.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04108831 |
| Source dataset | uspto-grants-1978_08 |
| ORD ID | ord-f0c1fb9c087449b281bbb90694ed55ab |
| Source note | uspto-grants-1978_08 |