Ethanol → HCID 20312376, compound

HRID 2420029Notes

Reaction equation

HRID 2420029 reaction equation
[CH2:1]=[O:2].[CH2:3]([NH2:15])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[CH3:16][C:17]1[C:18]([OH:26])=[C:19]([CH3:25])[C:20]([CH3:24])=[C:21]([CH:23]=1)O.[CH2:27](O)C>>[CH2:3]([N:15]1[CH2:24][C:20]2[C:19]([CH3:25])=[C:18]([OH:26])[C:17]([CH3:16])=[C:23]([CH3:27])[C:21]=2[O:2][CH2:1]1)[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]

Participants

5

Reactant 4

HCID 702Ethanol2×HCID 712FormaldehydeHCID 12785TrimethylhydroquinoneHCID 13583Dodecylamine

Product 1

HCID 20312376HCID 20312376, compound

Procedure

A mixture of paraformaldehyde (6.0 g., 0.2 mole) and dodecylamine (18.5 g., 0.1 mole) is refluxed in ethanol until nearly everything dissolves. A solution of 15.2 g. (0.1 mole) trimethylhydroquinone in 100 ml. of ethanol is added and is refluxed for 2 hr. On cooling, the product precipitates as a fluffy white solid. The yield is 19.3 g. The NMR spectrum confirms the structure.

Workup

  1. dissolutiondissolves
  2. temperatureis refluxed for 2 hr
  3. temperatureOn cooling
  4. customthe product precipitates as a fluffy white solid

Sources & evidence

ORD record
ord-e70d403aae844dfd9bda679607f0d360
Source dataset
uspto-grants-1978_08
Patent number
US04108850

Reaction notes

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