HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → 3-Phenoxybenzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Hexamethylenetetramine | HCID 4101 | — |
| Reactant | 3-Phenoxybenzyl chloride | HCID 93291 | — |
| Reactant | 1-(Dibromomethyl)-3-phenoxybenzene | HCID 104630 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 3-Phenoxybenzaldehyde | HCID 38284 | — |
Reaction Steps
A process according to claim 1, wherein the mixture of m-phenoxybenzyl bromide (II) and m-phenoxybenzal bromide (X = bromine) is reacted with 1 to 2 molar equivalents of hexamethylenetetramine in hot aqueous ethanol or hot aqueous acetic acid and hydrolyzing the mixture with dilute hydrochloric acid to yield m-phenoxybenzaldehyde (I).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04108904 |
| Source dataset | uspto-grants-1978_08 |
| ORD ID | ord-71e851d97ae94812a875733e9d2fd1f2 |
| Source note | uspto-grants-1978_08 |