Ammonia → HCID 53886440, compound

HRID 2420111Notes

Reaction equation

HRID 2420111 reaction equation
[CH2:1]([C:8]1[CH:9]=[CH:10][C:11]([C:14]([O:16]CC)=O)=[N:12][CH:13]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[NH3:19]>>[CH2:1]([C:8]1[CH:9]=[CH:10][C:11]([C:14]([NH2:19])=[O:16])=[N:12][CH:13]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 222AmmoniaHCID 20313024HCID 20313024, compound

Product 1

HCID 53886440HCID 53886440, compound

Procedure

To one gram of ethyl 5-benzylpicolinate, 10 ml. of 28% aqueous ammonia were added. After allowing the mixture to stand at room temperature for 24 hours, crystals formed were collected by filtration and recrystallized from ethanol to obtain 0.6 g of 5-benzylpicolinic acid amide as colorless crystals of a melting point of 193°~196° C.

Workup

  1. customcrystals formed
  2. filtrationwere collected by filtration
  3. customrecrystallized from ethanol

Sources & evidence

ORD record
ord-9d7561ad9af4449ba94e0238ef3a01f1
Source dataset
uspto-grants-1978_08
Patent number
US04109000

Reaction notes

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