Toluene → HCID 86620298, compound

HRID 2425134Notes

Reaction equation

HRID 2425134 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([C:10]2[C:11]([S:16]([OH:19])(=O)=[O:17])=[CH:12][CH:13]=[CH:14][CH:15]=2)[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].CN(C=O)C.C1(C)C=CC=CC=1.S(Cl)([Cl:34])=O>>[N+:1]([C:4]1[CH:5]=[C:6]([C:10]2[C:11]([S:16]([Cl:34])(=[O:19])=[O:17])=[CH:12][CH:13]=[CH:14][CH:15]=2)[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]

Participants

5

Reactant 4

HCID 1140TolueneHCID 6228DimethylformamideHCID 24386Thionyl ChlorideHCID 866202973'-Nitrobiphenyl sulfonic acid

Product 1

HCID 86620298HCID 86620298, compound

Procedure

3′-Nitrobiphenyl sulfonic acid (2 g) was refluxed in thionyl chloride (30 mL) with a catalytic quantity of DMF (0.5 mL) for 4 hours. Toluene was added and the solvents evaporated under vacuum. The residue was recrystallised from ethyl acetate/petrol to give the title compound as white crystals.

Workup

  1. customthe solvents evaporated under vacuum
  2. customThe residue was recrystallised from ethyl acetate/petrol

Sources & evidence

ORD record
ord-7c241e6b7ca343258d343f441161c898
Source dataset
uspto-grants-2011_06
Patent number
US07964643B2

Reaction notes

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