Dimethylformamide → HCID 178424119, compound

HRID 2427235Notes

Reaction equation

HRID 2427235 reaction equation
Br[C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][C:3]=1N.C(O[C:13]([SH:15])=[S:14])C.[K].C[N:18](C=O)C>>[SH:15][C:13]1[S:14][C:2]2[CH:3]=[CH:4][CH:5]=[C:6]([CH3:8])[C:7]=2[N:18]=1

Participants

5

Reactant 4

HCID 6228DimethylformamideHCID 8823Ethyl xanthateHCID 114222-Bromo-4-methylanilineHCID 5462222Potassium

Product 1

HCID 178424119HCID 178424119, compound

Procedure

The title compound was prepared using the method of example 239, starting with 2-bromo-4-methyl-phenylamine (Acros) (27.9 g), O-ethylxanthic acid, potassium salt (Lancaster, 54 g) in DMF (250 mL). The mercaptobenzothiazole 340 was obtained as an pale brown solid (27 g). Recrystalization from CHCl3 gave pinkish white crystals (20 g).

Workup

  1. customThe title compound was prepared

Sources & evidence

ORD record
ord-f16d47dc5a3f4fe8a8a497ed09c5b634
Source dataset
uspto-grants-2011_06
Patent number
US07968567B2

Reaction notes

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