HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → HCID 11947986, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Dimethylacetamide | HCID 31374 | — |
| Reactant | HCID 11947984 | HCID 11947984 | — |
| Reactant | Potassium tert-butoxide | HCID 23665647 | — |
| Reactant | HCID 86637438 | HCID 86637438 | — |
| Product | HCID 11947986 | HCID 11947986 | — |
Reaction Steps
A typical but not limiting example represents a reaction of 2-(1-propyl-4 methyl-6-(1′-methylbenzimidazole-2-yl)benzimidazole with 4-bromomethyl-2′-formylbiphenyl in N,N-dimethylacetamide with potassium tert-butoxide or potassium carbonate or sodium hydroxide as a base to give 4′-[(2-n-propyl-4-methyl-6-(1-methyl-imidazol-4-yl)-benzimidazol-1-yl)methyl]-biphenyl-2-carboxaldehyde. In another typical but not limiting example 4-bromomethyl-2′-formylbiphenyl reacts in similar conditions with 2-butyl-4,4-tetramethylene-4,5-dihydroimidazol-5-one to give 2-butyl-4,5-dihydro-1-((2′-formyl-4-biphenylyl)methyl)-4,4-tetramethyleneimidazol-5-one.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07968727B2 |
| Source dataset | uspto-grants-2011_06 |
| ORD ID | ord-838920ed2c634b84b71c73733bd7fa22 |
| Source note | uspto-grants-2011_06 |