Ceric ammonium nitrate → HCID 42599127, compound

HRID 2428240Notes

Reaction equation

HRID 2428240 reaction equation
[CH2:1]([N:3]([CH3:21])[C:4]([C:6]1([CH3:20])[CH2:15][CH2:14][C:13]2[C:8](=[C:9]([CH3:19])[C:10]([CH3:18])=[C:11]([OH:17])[C:12]=2[CH3:16])[O:7]1)=[O:5])[CH3:2].[O:22]=[N+]([O-])[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[Ce+4].[NH4+].[NH4+]>>[CH2:1]([N:3]([CH3:21])[C:4](=[O:5])[C:6]([OH:22])([CH3:20])[CH2:15][CH2:14][C:13]1[C:8](=[O:7])[C:9]([CH3:19])=[C:10]([CH3:18])[C:11](=[O:17])[C:12]=1[CH3:16])[CH3:2]

Participants

3

Reactant 2

HCID 180504Ceric ammonium nitrateHCID 67263078HCID 67263078, compound

Product 1

HCID 42599127HCID 42599127, compoundYield 92.3%

Procedure

Oxidation as described in protocol B, using 78 mg (0.268 mmol) of N-ethyl-6-hydroxy-N,2,5,7,8-pentamethylchroman-2-carboxamide and 323 mg CAN (0.590 mmol) yielded 76 mg of N-ethyl-2-hydroxy-N,2-dimethyl-4-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)butanamide as a yellow oil.

Sources & evidence

ORD record
ord-1526d45828cc473787cb671b3ae8e5a1
Source dataset
uspto-grants-2011_06
Patent number
US07968746B2

Reaction notes

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