HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aluminium lithium hydride → HCID 56652279, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Reactant | Tetrahydrofuran toluene | HCID 22635083 | — |
| Reactant | HCID 66920946 | HCID 66920946 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 56652279 | HCID 56652279 | — |
Reaction Steps
A solution of trans-2-Chloro-11-nitromethyl-10,11-dihydro-dibenzo[b,f]oxepine-10-carboxylic acid methyl ester (4) (4.6 g, 13.23 mmol) in dry THF (23 ml) is added at—15° C. to a mixture of THF (23 ml) and 3.5 M Lithium aluminum hydride (LAH) suspension in THF/Toluene (15.1 ml, 52.9 mmol).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08653280B2 |
| Source dataset | uspto-grants-2014_02 |
| ORD ID | ord-caf5f02d5b5d422089271bfb59d2d112 |
| Source note | uspto-grants-2014_02 |