Methyl iodide → 2-[[(2-Methoxybenzoyl) [4-(tetradecyloxy)benzoyl]amino]methyl]-1-methylpyridinium iodide

HRID 247917Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 247917
[CH3:1][O:2][C:3]1[CH:41]=[CH:40][CH:39]=[CH:38][C:4]=1[C:5]([N:7]([CH2:31][C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][N:33]=1)[C:8](=[O:30])[C:9]1[CH:14]=[CH:13][C:12]([O:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[CH:11][CH:10]=1)=[O:6].[CH3:42][I:43]>>[I-:43].[CH3:1][O:2][C:3]1[CH:41]=[CH:40][CH:39]=[CH:38][C:4]=1[C:5]([N:7]([CH2:31][C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][N+:33]=1[CH3:42])[C:8](=[O:30])[C:9]1[CH:10]=[CH:11][C:12]([O:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])=[CH:13][CH:14]=1)=[O:6]

Komponenten

3

Edukt 2

HCID 6328Methyl iodideHCID 190164342-Methoxy-N-(2-pyridinylmethyl)-N-[4-(tetradecyloxy)benzoyl]benzamide

Produkt 1

HCID 678789492-[[(2-Methoxybenzoyl) [4-(tetradecyloxy)benzoyl]amino]methyl]-1-methylpyridinium iodide

Reaktionsbedingungen

Temperatur
105 °C

Versuchsvorschrift

A mixture of 0.770 g of product from Example 6 and 4.29 ml methyl iodide is heated in a sealed tube at 105° C. for 15 hours. The cooled reaction is concentrated in vacuo to give 0.960 g of the desired product as a thick yellow oil which solidified on standing.

Aufarbeitung

  1. customThe cooled reaction
  2. concentrationis concentrated in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-8162f06ca7e64419b0505c424ce402f8
Quelldatensatz
uspto-grants-1993_05
Patentnummer
US05208247

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