HCID 12361482, compound → HCID 10313957, compound

HRID 247931Notes

Reaction equation

HRID 247931 reaction equation
C[O:2][C:3](=O)[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].[H-].[Al+3].[Li+].[H-].[H-].[H-]>O1CCCC1>[CH2:11]([O:10][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=1[CH2:3][OH:2])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

Participants

4

Reactant 2

HCID 12361482HCID 12361482, compoundHCID 21226445Aluminium lithium hydride

Product 1

HCID 10313957HCID 10313957, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The title compound is prepared by the procedure of Example 19 using 20.0 g of product from Example 17, 200 ml of dry tetrahydrofuran and 6.53 g of lithium aluminum hydride. The reaction is stirred at room temperature for 60 hours. The product, 18.4 g, is obtained as colorless crystals.

Workup

  1. customThe product, 18.4 g, is obtained as colorless crystals

Sources & evidence

ORD record
ord-afbb341023b643e2879f9ac38f5f0a86
Source dataset
uspto-grants-1993_05
Patent number
US05208247

Reaction notes

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