HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 248309Generated: October 25, 2026
(Diethylamino)sulfur trifluoride → HCID 178447877, compound
https://huagongshe.com/reaction/248309
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | (Diethylamino)sulfur trifluoride | HCID 123472 | — |
| Reactant | (Trifluoromethyl)trimethylsilane | HCID 552549 | — |
| Reactant | Tetrabutylammonium Fluoride | HCID 2724141 | — |
| Reactant | HCID 178447904 | HCID 178447904 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 178447877 | HCID 178447877 | — |
Reaction Steps
A mixture of 10 mmol of 4-(trans-4-propylcyclohexyl)cyclohexanone, 11 mmol of trimethyl(trifluoromethyl)silane, 10 mmol of tetrabutylammonium fluoride and 50 ml of THF is stirred for 2 hours at 0° C. After customary work-up, the crude product is dissolved in 20 mml of THF, 10 mmol of DAST are added, and the mixture is heated to boiling. After customary work-up, the crude product is purified by chromatography and crystallization.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05209868 |
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| Source dataset | uspto-grants-1993_05 |
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| ORD ID | ord-93000c1993c1467d8c958cf156ab0696 |
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| Source note | uspto-grants-1993_05 |
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