HRID248791

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：[Na+].c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID2723787

Borate(1-), tetraphenyl-, sodium

C24H20BNa

HCID19762119

未命名化合物

PRODUCTS

生成物

结构：O=C(OCC[n+]1ccccc1)c1ccccc1.c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID19432278

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID962

Water

H2O

4 次

PROCEDURE

实验过程

A solution of 17.11 grams (0.05 mol) of sodium tetraphenylborate in 50 milliters of water was added to a solution of 15.41 grams (0.05 mol) of N-(2-benzoyloxyethyl)pyridinium bromide, prepared as described in Example 2, in 50 milliters of water. An additional 200 milliters of water was added and the mixture was stirred and allowed to stand for 1 hr. The mixture was diluted with more water and filtered. The solid collected was washed with water and dried. Recrystallization from acetonitrile gave 15.5 grams (56.62% of theory) of product; mp=135°-138° C.

WORKUP

后处理

customprepared
filtrationfiltered
customThe solid collected
washwas washed with water
customdried
customRecrystallization from acetonitrile
customgave 15.5 grams (56.62% of theory) of product

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-10494a6bc51e4ddbb6ca5e45aac55d71
来源数据集: uspto-grants-1993_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05212035
来源说明: uspto-grants-1993_05

反应 SMILES

[C:1]1([B-:7]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Na+].[Br-].[C:28]([O:36][CH2:37][CH2:38][N+:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1)(=[O:35])[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1>O>[C:20]1([B-:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)([C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=2)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1.[C:28]([O:36][CH2:37][CH2:38][N+:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1)(=[O:35])[C:29]1[CH:30]=[CH:31][CH:32]=[CH:33][CH:34]=1