HRID248794

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：[Na+].c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID2723787

Borate(1-), tetraphenyl-, sodium

C24H20BNa

HCID19762112

未命名化合物

PRODUCTS

生成物

结构：CC(=O)OCC[n+]1ccccc1.c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID19762114

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID962

Water

H2O

3 次

PROCEDURE

实验过程

To a solution of 24.61 grams (0.10 mol) of N-(2-acetyloxyethyl)pyridinium bromide in 250 milliters of water there was added a solution of 34.24 grams (0.10 mol) of sodium tetraphenylborate in 150 milliters of water. An oily precipitate formed which was treated with 500 milliters of water to give a white solid. The solid was collected and recrystallized from acetonitrile. The yield of product was 39.8 grams (81.99 % of theory); mp=223°-224° C.

WORKUP

后处理

customAn oily precipitate formed which
customto give a white solid
customThe solid was collected
customrecrystallized from acetonitrile

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-16349dba04d647b7967b8f55725171d1
来源数据集: uspto-grants-1993_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05212035
来源说明: uspto-grants-1993_05

反应 SMILES

[Br-].[C:2]([O:5][CH2:6][CH2:7][N+:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)(=[O:4])[CH3:3].[C:14]1([B-:20]([C:33]2[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=2)([C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)[C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[Na+]>O>[C:33]1([B-:20]([C:14]2[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=2)([C:21]2[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=2)[C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)[CH:34]=[CH:35][CH:36]=[CH:37][CH:38]=1.[C:2]([O:5][CH2:6][CH2:7][N+:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)(=[O:4])[CH3:3]