n-Cyanomethyl-n-methylsulphonyl-4-nitroaniline → 4-(N-cyanomethyl-N-methylsulphonyl-amino)-aniline

HRID 24885Notes

Reaction equation

HRID 24885 reaction equation
[C:1]([CH2:3][N:4]([S:14]([CH3:17])(=[O:16])=[O:15])[C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-])=O)=[CH:7][CH:6]=1)#[N:2]>CN(C=O)C>[C:1]([CH2:3][N:4]([C:5]1[CH:10]=[CH:9][C:8]([NH2:11])=[CH:7][CH:6]=1)[S:14]([CH3:17])(=[O:16])=[O:15])#[N:2]

Participants

3

Reactant 1

HCID 22569517n-Cyanomethyl-n-methylsulphonyl-4-nitroaniline

Product 1

HCID 225695404-(N-cyanomethyl-N-methylsulphonyl-amino)-aniline

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Prepared analogously to Example 39c by catalytic hydrogenation of N-cyanomethyl-N-methylsulphonyl-4-nitroaniline in DMF.

Sources & evidence

ORD record
ord-91440e6526c445f498c4dd830af6d05f
Source dataset
uspto-grants-2005_02
Patent number
US06855710B2

Reaction notes

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