Chlorotrimethylsilane → HCID 131724740, compound

HRID 24978Notes

Reaction equation

HRID 24978 reaction equation
[CH3:1][Si:2]([CH3:5])([CH3:4])Cl.[CH3:6][C:7]1([C:13]2([Li])C=CC=C2)[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1>C1COCC1>[CH3:6][C:7]1([CH2:13][Si:2]([CH:5]2[CH:9]=[CH:8][CH:7]=[CH:6]2)([CH3:4])[CH3:1])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]1

Participants

4

Reactant 2

HCID 6397ChlorotrimethylsilaneHCID 178506635HCID 178506635, compound

Product 1

HCID 131724740HCID 131724740, compoundYield 57%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

Trimethylchlorsilane (29.1 g, 268 mmol) was slowly added to a solution of (1-methyl-cyclohexyl)cyclopentadienyllithium (43.34 g, 258 mmol) in THF (350 ml). After refluxing the mixture for 3,5 h, the solvent was removed in vacuo and the residue was distilled under reduced pressure to give (1-methylcyclohexyl)cyclopentadienyltrimethylsilane as yellow oil.

Workup

  1. temperatureAfter refluxing the mixture for 3,5 h
  2. customthe solvent was removed in vacuo
  3. distillationthe residue was distilled under reduced pressure

Sources & evidence

ORD record
ord-e8d572084c7b43878787008ce08b34db
Source dataset
uspto-grants-2005_02
Patent number
US06858558B2

Reaction notes

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