huagongshe.com
HRID251024

反应详情

EQUATION

反应方程式

HRID 251024 的结构方程式

REACTANTS

反应物

3
结构：Cc1cccnc1C=O
HCID1501874

3-methylpyridine-2-carbaldehyde

C7H7NO

结构：Cc1cccnc1CN
HCID1514370

未命名化合物

结构：CC(=O)O[BH-](OC(C)=O)OC(C)=O.[Na+]
HCID5049666

Sodium triacetoxyborohydride

C6H10BNaO6

PRODUCTS

生成物

1
结构：Cc1cccnc1CNCc1ncccc1C
HCID45098010

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClCCl
溶剂HCID6344

Dichloromethane

CH2Cl2

PROCEDURE

实验过程

Using General Procedure B: Reaction of 3-methyl-2-aminomethylpyridine and 3-methyl-2-pyridinecarboxaldehyde in CH2Cl2 with NaBH(OAc)3 gave bis-(3-methyl-pyridin-2-ylmethyl)-amine as a yellow oil. 1H NMR (CDCl3) δ 2.33 s, 6H), 4.06 (s, 4H), 7.08 (dd, 2H, J=9, 6 Hz), 7.42 (dd, 2H, J=9, 3 Hz), 8.41 (d, 2H, J=3 Hz).