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Azobisisobutyronitrile → 2-Phenylethenesulfonic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Azobisisobutyronitrile | HCID 6547 | — |
| 反応物 | Perfluorooct-1-ene | HCID 2782409 | — |
| 反応物 | Sodium styrenesulfonate | HCID 53627496 | — |
| 溶媒 | Dimethyl Sulfoxide | HCID 679 | — |
| 生成物 | 2-Phenylethenesulfonic acid | HCID 74864 | — |
反応手順
19 g of sodium styrenesulfonate (SSNa) (available from Sigma-Aldrich Corp.) and 1 g of branched perfluorooctene (heptafluoro-3,3-bis(trifluoromethyl)-1-hexene) are fully dissolved in 0.24 L of dimethylsulfoxide (DMSO) with heating. Then, 0.1 g of azobisisobutyronitrile (AIBN) is added dropwise to the DMSO solution. The monomers are polymerized for 24 hours or more. The polymerization is carried out varying the content of the branched perfluorooctene (5, 10, and 20 wt %).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07875208B2 |
| 出典データセット | uspto-grants-2011_01 |
| ORD ID | ord-edf865c9d65745a9ab3f6d0f1a499dd6 |
| 出典メモ | uspto-grants-2011_01 |