Iodoethane → HCID 58951882, compound

HRID 254592Notes

Reaction equation

HRID 254592 reaction equation
[CH2:1]([C:3]1[C:10]([OH:11])=[CH:9][CH:8]=[C:7]([CH2:12][CH3:13])[C:4]=1[CH:5]=[O:6])[CH3:2].C(=O)([O-])[O-].[Cs+].[Cs+].I[CH2:21][CH3:22]>>[CH2:21]([O:11][C:10]1[C:3]([CH2:1][CH3:2])=[C:4]([C:7]([CH2:12][CH3:13])=[CH:8][CH:9]=1)[CH:5]=[O:6])[CH3:22]

Participants

4

Reactant 3

HCID 6340IodoethaneHCID 10796Cesium carbonateHCID 58951851HCID 58951851, compound

Product 1

HCID 58951882HCID 58951882, compound

Procedure

3-Ethoxy-2,6-diethyl-benzaldehyde was prepared from 2,6-diethyl-3-hydroxy-benzaldehyde, cesium carbonate and iodoethane in analogy to Example 213b): yellow oil; 1H-NMR (CDCl3): 1.21 (3H, t, CH3), 1.23 (3H, t, CH3), 1.43 (3H, t, CH3), 2.86 (2H, q, CH2), 2.96 (2H, q, CH2), 4.04 (2H, q, OCH2), 6.96 (1H, d, ArH), 7.05 (1H, d, ArH), 10.57 (1H, s, CH═O).

Sources & evidence

ORD record
ord-767d0f028d1740b3a0615ec8f8451d9e
Source dataset
uspto-grants-2011_01
Patent number
US07875645B2

Reaction notes

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