Phenylboronic Acid → HCID 58951898, compound

HRID 254601Notes

Reaction equation

HRID 254601 reaction equation
[CH2:1]([C:3]1[C:10]([OH:11])=[CH:9][CH:8]=[C:7]([CH2:12][CH3:13])[C:4]=1[CH:5]=[O:6])[CH3:2].[C:14]1(B(O)O)[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>>[CH2:1]([C:3]1[C:10]([O:11][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[CH:9][CH:8]=[C:7]([CH2:12][CH3:13])[C:4]=1[CH:5]=[O:6])[CH3:2]

Participants

3

Reactant 2

HCID 66827Phenylboronic AcidHCID 58951851HCID 58951851, compound

Product 1

HCID 58951898HCID 58951898, compound

Procedure

2,6-Diethyl-3-phenoxy-benzaldehyde was prepared from 2,6-diethyl-3-hydroxy-benzaldehyde and phenylboronic acid in analogy to Example 219a): yellow oil; 1H-NMR (CDCl3): 1.20 (3H, t, CH3), 1.25 (3H, t, CH3), 2.93 (2H, q, CH2), 2.98 (2H, q, CH2), 6.91 (2H, d, 2×ArH), 7.00-7.10 (3H, m, 3×ArH), 7.28-7.38 (2H, m, 2×ArH), 10.6 (1H, s, CHO).

Sources & evidence

ORD record
ord-9b5607c5ddf544aba0ebb3cc63a6a2a7
Source dataset
uspto-grants-2011_01
Patent number
US07875645B2

Reaction notes

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