Ethanethiol → HCID 14013757, compound

HRID 255413Notes

Reaction equation

HRID 255413 reaction equation
[F:1][C:2]([F:24])([F:23])[C:3]1[C:8]([C:9]([O:11][CH2:12][CH3:13])=[O:10])=[C:7](Cl)[C:6]([C:15]([O:17][CH3:18])=[O:16])=[C:5]([C:19]([F:22])([F:21])[F:20])[N:4]=1.C([O-])([O-])=O.[K+].[K+].[CH2:31]([SH:33])[CH3:32]>CC(C)=O>[CH2:31]([S:33][C:7]1[C:6]([C:15]([O:17][CH3:18])=[O:16])=[C:5]([C:19]([F:20])([F:21])[F:22])[N:4]=[C:3]([C:2]([F:24])([F:23])[F:1])[C:8]=1[C:9]([O:11][CH2:12][CH3:13])=[O:10])[CH3:32]

Participants

5

Reactant 3

HCID 6343EthanethiolHCID 11430Potassium CarbonateHCID 14013761HCID 14013761, compound

Product 1

HCID 14013757HCID 14013757, compoundYield 58.8%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

This material was pepared as described in Example 11: 3.36 g (0.009 mol) of product of Example 27, 0.86 g (0.006 mol) of K2CO3 and 12 ml (0.180 mol) of ethanethiol in 25 ml of acetone were reacted affording an orange oil which was kugelrohr distilled at 33 Pa, pot temperature 79° to give 2.11 g (58.8%) of product as a clear oil, nD25 1.4507.

Workup

  1. customaffording an orange oil which
  2. distillationwas kugelrohr distilled at 33 Pa, pot temperature 79°

Sources & evidence

ORD record
ord-2d53bde52585428eb441e37e7cd96ac0
Source dataset
uspto-grants-1987_10
Patent number
US04698093

Reaction notes

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