反应详情

58.30 Grams of 2,3-dichloro-1-propene were added dropwise to a mixture of 30.00 g of heptanol, 90 g of toluene, 120 g of water and 34.35 g of zinc powder at 45° C., and then, the resultant mixture was allowed to react at the same temperature for 10 hours. After the reaction finished, zinc-derived insolubles were filtered off, and the resultant filtrate was subjected to separation. The organic phase was washed with a 7% sodium carbonate aqueous solution and then dried over sodium sulfate. The desiccant was filtered off, and then the toluene was distilled off under reduced pressure to give 47.14 g of 2-chloroallyl-n-hexyl-carbinol. The results were as follows.

1. customto react at the same temperature for 10 hours
2. filtrationwere filtered off
3. customthe resultant filtrate was subjected to separation
4. washThe organic phase was washed with a 7% sodium carbonate aqueous solution
5. dry with materialdried over sodium sulfate
6. filtrationThe desiccant was filtered off
7. distillationthe toluene was distilled off under reduced pressure