Methanol → HCID 19785974, compound

HRID 256746Notes

Reaction equation

HRID 256746 reaction equation
[CH3:1][CH:2]([CH2:13][Cl:14])[CH2:3][Si:4]([CH:7]1[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)(Cl)Cl.[CH3:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[CH2:21]([OH:27])[CH2:22][CH2:23][CH2:24][CH2:25][CH3:26].C[OH:29]>>[CH3:1][CH:2]([CH2:13][Cl:14])[CH2:3][Si:4]([CH:7]1[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([O:27][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[O:29][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]

Participants

5

Reactant 4

HCID 887MethanolHCID 8058HexaneHCID 81031-HexanolHCID 19785979HCID 19785979, compound

Product 1

HCID 19785974HCID 19785974, compound

Procedure

The apparatus was identical to that described in Example 1. 1367 g (5 mols) of (2-methyl-3-chloropropyl)-cyclohexyl-dichlorosilane were introduced into the flask together with 900 ml of hexane. The esterification was performed as described in Example 1. However, in place of methanol, two portions of 510 g (5 mols) each of n-hexanol were used. The raw reaction product was worked up by distillation in vacuo. The structure of the reaction product was elucidated by elemental and GC/MS analysis.

Workup

  1. customThe raw reaction product
  2. distillationwas worked up by distillation in vacuo

Sources & evidence

ORD record
ord-71c15eb74d3741af9a9d64b8020d260f
Source dataset
uspto-grants-1993_11
Patent number
US05258536

Reaction notes

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