HCID 53983035, compound → HCID 86747349, compound

HRID 256786Notes

Reaction equation

HRID 256786 reaction equation
[CH3:1][N:2]([CH:4]=[C:5]1[CH2:10][CH:9]=[CH:8][C:7](=[CH:11][N:12]([CH3:14])[CH3:13])[CH:6]1Br)[CH3:3].C([Li])CCC.[Cl-].[CH3:22][In+:23][CH3:24]>CCCCCC>[CH3:1][N:2]([CH:4]=[C:5]1[CH2:10][CH:9]=[CH:8][C:7](=[CH:11][N:12]([CH3:14])[CH3:13])[CH:6]1[In:23]([CH3:24])[CH3:22])[CH3:3]

Participants

5

Reactant 3

HCID 53983035HCID 53983035, compoundHCID 178418339ButyllithiumHCID 178477775HCID 178477775, compound

Product 1

HCID 86747349HCID 86747349, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent2×

Procedure

2.71 g (10.0 mmol) of 2,6-bis(dimethylaminomethylene)phenyl bromide in 40 ml of hexane, 6.3 ml of n-butyllithium (10.0 mmol; 1.6 mol/l in hexane) and 1.8 g (10.0 mmol) of dimethylindium chloride in 20 ml of hexane are reacted analogously to Example 1 to give [2,6-bis(di-methylaminomethylene)phenyl] dimethylindium, which is obtained in the form of colorless crystals, m.p. 53° C., by cooling a concentrated hexane solution to -30° C.

Sources & evidence

ORD record
ord-a3b3e0f6bb08436aa6bdff7b402d9246
Source dataset
uspto-grants-1993_11
Patent number
US05259915

Reaction notes

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