HCID 54293641, compound → HCID 86747350, compound

HRID 256787Notes

Reaction equation

HRID 256787 reaction equation
[CH2:1]([N:3]([CH:6]=[C:7]1[CH2:12][CH:11]=[CH:10][C:9](=[CH:13][N:14]([CH2:17][CH3:18])[CH2:15][CH3:16])[CH:8]1Br)[CH2:4][CH3:5])[CH3:2].C([Li])CCC.[Cl-].[CH2:26]([In+:28][CH2:29][CH3:30])[CH3:27]>CCCCCC>[CH2:1]([N:3]([CH:6]=[C:7]1[CH2:12][CH:11]=[CH:10][C:9](=[CH:13][N:14]([CH2:17][CH3:18])[CH2:15][CH3:16])[CH:8]1[In:28]([CH2:29][CH3:30])[CH2:26][CH3:27])[CH2:4][CH3:5])[CH3:2]

Participants

5

Reactant 3

HCID 54293641HCID 54293641, compoundHCID 178418339ButyllithiumHCID 178461624HCID 178461624, compound

Product 1

HCID 86747350HCID 86747350, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent2×

Procedure

2.4 g (7.3 mmol) of 2,6-bis(diethylaminomethylene)phenyl bromide in 40 ml of hexane, 4.6 ml of butyllithium (7.3 mmol; 1.6 mol/l in hexane) and 1.5 g (7.3 mmol) of diethylindium chloride in 20 ml hexane are reacted analogously to Example 1 to give [2,6-bis(diethylaminomethylene)phenyl]diethylindium, which is obtained as a colorless liquid, b.p. 115° C./0.04 mbar, by vacuum distillation.

Sources & evidence

ORD record
ord-3a6792b2a97f420a80d370938b1feeb0
Source dataset
uspto-grants-1993_11
Patent number
US05259915

Reaction notes

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