m-Chloroperbenzoic acid → HCID 19782074, compound

HRID 257816Notes

Reaction equation

HRID 257816 reaction equation
[Cl:1][C:2]1[CH:18]=[CH:17][C:5]([CH2:6][CH:7]2[C:13](=[CH2:14])[C:12]([CH3:16])([CH3:15])[CH2:11][CH2:10][CH2:9][CH2:8]2)=[CH:4][CH:3]=1.ClC1C=CC=C(C(OO)=[O:27])C=1.[OH-].[Ca+2].[OH-]>C(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:18]=[CH:17][C:5]([CH2:6][CH:7]2[C:13]3([O:27][CH2:14]3)[C:12]([CH3:15])([CH3:16])[CH2:11][CH2:10][CH2:9][CH2:8]2)=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 70297m-Chloroperbenzoic acidHCID 6093208Calcium HydroxideHCID 19782078HCID 19782078, compound

Product 1

HCID 19782074HCID 19782074, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

In 5 ml of chloroform was dissolved 340 mg of 7-(4-chlorobenzyl)-2,2-dimethyl-1-methylenecycloheptane [Compound (III-3) in Table III), and then 450 mg of m-chloroperbenzoic acid was added to the mixture over 10 minutes and the mixture was stirred at room temperature for one hour. Next, 385 mg of calcium hydroxide was added and the mixture was stirred at room temperature for 10 minutes.

Workup

  1. additionwas added to the mixture over 10 minutes
  2. stirringthe mixture was stirred at room temperature for 10 minutes

Sources & evidence

ORD record
ord-39c6f8abba364dc9adffa3bf79ec7172
Source dataset
uspto-grants-1993_11
Patent number
US05264450

Reaction notes

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