Glycerol → HCID 68125393, compound

HRID 258590Notes

Reaction equation

HRID 258590 reaction equation
[CH:1]1([CH3:13])[CH2:6][CH2:5][CH:4]([CH:7]([CH3:9])[CH3:8])[CH:3]([C:10](Cl)=[O:11])[CH2:2]1.[OH:14][CH2:15][CH:16]([CH2:18][OH:19])[OH:17]>O>[CH:1]1([CH3:13])[CH2:6][CH2:5][CH:4]([CH:7]([CH3:9])[CH3:8])[CH:3]([C:10]([O:14][CH2:15][CH:16]([CH2:18][OH:19])[O:17][C:10]([CH:3]2[CH:4]([CH:7]([CH3:9])[CH3:8])[CH2:5][CH2:6][CH:1]([CH3:13])[CH2:2]2)=[O:11])=[O:11])[CH2:2]1

Participants

4

Reactant 2

HCID 753GlycerolHCID 13734319Cyclohexanecarbonyl chloride, 5-methyl-2-(1-methylethyl)-

Product 1

HCID 68125393HCID 68125393, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of p-menth-3-oyl chloride (2 g.) and glycerol (20 ml.) was heated at 100° for 4 hours. The mixture was then poured into water (600 ml.) and extracted 3 times with ether. The extracts were dried (MgSO4) and the solvent removed under reduced pressure to leave 1,2-bis-(p-menth-3-oyl)glycerol as a colourless oil (1.2 g.).

Workup

  1. temperaturewas heated at 100° for 4 hours
  2. extractionextracted 3 times with ether
  3. dry with materialThe extracts were dried (MgSO4)
  4. customthe solvent removed under reduced pressure

Sources & evidence

ORD record
ord-2cce7e969fd3433e9bccccdf5a4e3333
Source dataset
uspto-grants-1977_07
Patent number
US04033994

Reaction notes

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