反应详情

温度

0 °C

Alternatively, the 0.1 moles of the synthesized tri-n-decylcarbinol was added to 0.2 liters of methylene chloride. The mixture was covered with a blanket of nitrogen and cooled to 0° C. 0.050 mole titanium tetrachloride was added to the mixture and the solution was stirred 2-3 hours at 0° C. 0.066 mole trimethylaluminum was added and the mixture was allowed to warm to room temperature. The reaction was quenched with water and washed with 0.1 liter of a 20% HCl solution. The organic layer was dried with magnesium sulfate and the methylene chloride removed to give a yield of 70% tri-n-decylmethylmethane.

1. temperatureto warm to room temperature
2. customThe reaction was quenched with water
3. washwashed with 0.1 liter of a 20% HCl solution
4. dry with materialThe organic layer was dried with magnesium sulfate
5. customthe methylene chloride removed