m-Chloroperbenzoic acid → HCID 86734942, compound

HRID 259050Notes

Reaction equation

HRID 259050 reaction equation
[C:1]([O:4][CH2:5][CH2:6][CH:7]([CH:9]1[CH2:14][CH2:13][C:12]([CH3:15])=[CH:11][CH2:10]1)[CH3:8])(=[O:3])[CH3:2].ClC1C=CC=C(C(OO)=[O:24])C=1>C(Cl)Cl>[C:1]([O:4][CH2:5][CH2:6][CH:7]([CH:9]1[CH2:14][CH2:13][C:12]2([O:24][CH:11]2[CH2:10]1)[CH3:15])[CH3:8])(=[O:3])[CH3:2]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 20313892HCID 20313892, compound

Product 1

HCID 86734942HCID 86734942, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

The procedure of Example 1 was followed for the epoxidation of 4.2g (0.02 mole) of acetic acid, 3-(4-methyl-3-cyclohexenyl)butyl ester using 4.1g (0.02 mole) of 85% m-chloroperbenzoic acid in 150 ml of methylene chloride. Obtained was 4.1g of pure acetic acid, 3-(3,4-epoxy-4-methylcyclohexyl) butyl ester as a clear, colorless liquid. (See Table I).

Workup

  1. customObtained

Sources & evidence

ORD record
ord-cf4b86bf7c8f48238c9e91af97c655b2
Source dataset
uspto-grants-1977_07
Patent number
US04036629

Reaction notes

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