Acetic Acid → HCID 21423240, compound

HRID 259148Notes

Reaction equation

HRID 259148 reaction equation
[Cl:1][CH2:2][S:3][C:4]1[CH:9]=[CH:8][C:7]([N:10]2[CH:14]=[N:13][N:12]=[N:11]2)=[CH:6][CH:5]=1.OO.C(O)(=[O:19])C.[OH2:21]>>[Cl:1][CH2:2][S:3]([C:4]1[CH:9]=[CH:8][C:7]([N:10]2[CH:14]=[N:13][N:12]=[N:11]2)=[CH:6][CH:5]=1)(=[O:19])=[O:21]

Participants

5

Reactant 4

HCID 176Acetic AcidHCID 784Hydrogen PeroxideHCID 962WaterHCID 21423225HCID 21423225, compound

Product 1

HCID 21423240HCID 21423240, compound

Procedure

A solution of 226 mg. of 1-[p-(chloromethylthio)phenyl]-1H-tetrazole and 0.35 ml. of 30% hydrogen peroxide in 2 ml. of glacial acetic acid was refluxed 15 minutes, cooled, and diluted with water. Crystals filtered off and recrystallized from ethanol gave m.p. 168°-171.5° C.

Workup

  1. temperaturecooled
  2. filtrationCrystals filtered off
  3. customrecrystallized from ethanol
  4. customgave m.p. 168°-171.5° C.

Sources & evidence

ORD record
ord-8a0ed38ba81245d38453fd98603bf988
Source dataset
uspto-grants-1977_07
Patent number
US04036849

Reaction notes

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