HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosgene → 1-Chlorocarbonyl-2-oxo-3-(5-methylfurylideneamino)-imidazolidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosgene | HCID 6371 | — |
| Reactant | Chlorotrimethylsilane | HCID 6397 | — |
| Reactant | 1-(5-Methylfurylideneamino)-2-oxo-imidazolidine | HCID 70569531 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | 1-Chlorocarbonyl-2-oxo-3-(5-methylfurylideneamino)-imidazolidine | HCID 86736435 | — |
Reaction Steps
50.0 pts. by wt. of 1-(5-methylfurylideneamino)-2-oxo-imidazolidine, 84.3 pts. by wt. of triethylamine, 84.0 pts. by wt. of chlorotrimethylsilane and 51.4 pts. by wt. of phosgene are reacted as in Example 1.2. After recrystallisation from acetonitrile, 50.7 pts. by wt. of 1-chlorocarbonyl-2-oxo-3-(5-methylfurylideneamino)-imidazolidine of dec. pt. 180°-186° C. are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04147693 |
| Source dataset | uspto-grants-1979_04 |
| ORD ID | ord-61c674c012814e978cf7aa49b83a0cf6 |
| Source note | uspto-grants-1979_04 |