Potassium Carbonate → HCID 21423895, compound

HRID 259270Notes

Reaction equation

HRID 259270 reaction equation
C(O)(=O)C(O)=O.[CH2:7]([O:19][CH2:20][CH:21]([O:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])[CH2:22][N:23]1[CH:27]=[CH:26][N:25]=[CH:24]1)[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].C(=O)([O-])[O-].[K+].[K+]>ClCCl>[CH2:7]([O:19][CH2:20][CH:21]([O:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])[CH2:22][N:23]1[CH:27]=[CH:26][N:25]=[CH:24]1)[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 21423894HCID 21423894, compound

Product 1

HCID 21423895HCID 21423895, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

1-[3'-(n-dodecyloxy)-2'-(n-heptyloxy)propyl]imidazole oxalate (2.3 g.) in 100 ml. of dichloromethane is shaken with excess dilute potassium carbonate solution until the salt is completely dissolved. The organic layer is then separated, washed twice with water, dried over mgnesium sulfate and evaporated to yield 1-[3'-(n-dodecyloxy)-2'-(n-heptyloxy)propyl]imidazole as a gum.

Workup

  1. dissolutionis completely dissolved
  2. customThe organic layer is then separated
  3. washwashed twice with water
  4. dry with materialdried over mgnesium sulfate
  5. customevaporated

Sources & evidence

ORD record
ord-f00fefc52a0f45eeb981a043fec0f16e
Source dataset
uspto-grants-1977_07
Patent number
US04036974

Reaction notes

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