Potassium Carbonate → HCID 21423690, compound

HRID 259277Notes

Reaction equation

HRID 259277 reaction equation
[N+]([O-])(O)=O.[Cl:5][C:6]1[CH:11]=[CH:10][C:9]([S:12][CH:13]([CH2:20][S:21][C:22]2[CH:27]=[CH:26][C:25]([Cl:28])=[CH:24][CH:23]=2)[CH2:14][N:15]2[CH:19]=[CH:18][N:17]=[CH:16]2)=[CH:8][CH:7]=1.C(=O)([O-])[O-].[K+].[K+]>ClCCl>[Cl:5][C:6]1[CH:11]=[CH:10][C:9]([S:12][CH:13]([CH2:20][S:21][C:22]2[CH:23]=[CH:24][C:25]([Cl:28])=[CH:26][CH:27]=2)[CH2:14][N:15]2[CH:19]=[CH:18][N:17]=[CH:16]2)=[CH:8][CH:7]=1

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 21423695HCID 21423695, compound

Product 1

HCID 21423690HCID 21423690, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

1-[2',3'-Bis(4"-chlorophenylthio)propyl]imidazole nitrate (2.3 g.) in 100 ml. of dichloromethane is shaken with excess dilute potassium carbonate solution until the salt is completely dissolved. The organic layer is then separated, washed twice with water, dried over magnesium sulfate and evaporated to yield 1-[2',3'-bis(4"-chlorophenylthio)propyl]-imidazole as a mobile gum.

Workup

  1. dissolutionis completely dissolved
  2. customThe organic layer is then separated
  3. washwashed twice with water
  4. dry with materialdried over magnesium sulfate
  5. customevaporated

Sources & evidence

ORD record
ord-753b6b683b1f49a9888c93807676bc40
Source dataset
uspto-grants-1977_07
Patent number
US04036970

Reaction notes

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