Dimethylamine → Carbon Dioxide

HRID 259496Notes

Reaction equation

HRID 259496 reaction equation
[CH3:1][NH:2][CH3:3].[N+:4]([O-])([N+:6]([O-:8])=[O:7])=[O:5].[C:10](=O)([O-:12])[O-:11].[K+:14].[K+]>>[N:4]([N:2]([CH3:3])[CH3:1])=[O:5].[N+:6]([O-:8])([O-:11])=[O:7].[K+:14].[C:10](=[O:12])=[O:11]

Participants

6

Reactant 3

HCID 674DimethylamineHCID 11430Potassium CarbonateHCID 25352Nitrogen oxide (N2O4)

Product 3

HCID 280Carbon DioxideHCID 6124N-NitrosodimethylamineHCID 24434Potassium Nitrate

Procedure

nitrosating an aqueous solution of dimethylamine by reaction with dinitrogen tetraoxide and potassium carbonate at a pressure from atomospheric to 50 psig and a temperature from -10° C. to 40° C. to produce an aqueous solution of N-nitrosodimethylamine and potassium nitrate and gaseous carbon dioxide; and,

Sources & evidence

ORD record
ord-d22cce9da9e1496c8f357a98410c1ab1
Source dataset
uspto-grants-1977_07
Patent number
US04038321

Reaction notes

Loading…