HRID259656

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID126

p-Hydroxybenzaldehyde

C7H6O2

HCID7469

4-Hydroxyacetophenone

C8H8O2

HCID8375

2-Hydroxyacetophenone

C8H8O2

PRODUCTS

生成物

HCID19596236

1-[4-(3-Phenylpropoxy)phenyl]ethanone

C17H18O2

HCID21422420

未命名化合物

HCID21422440

1-[3-(3-Phenylpropoxy)phenyl]ethan-1-one

C17H18O2

PROCEDURE

实验过程

Following essentially the same procedure, but substituting o-hydroxyacetophenone, m-hydroxyacetophenone, and p-hydroxyacetophenone for the p-hydroxybenzaldehyde above, results in the formation of o-(3-phenylpropoxy)acetophenone (b.p. 173°-8° C. at 0.1 mm), m-(3-phenylpropoxy)acetophenone (b.p. 199°-201° C. at 0.2 mm) and p-(3-phenylpropoxy) acetophenone (m.p. 80°-1° C.), respectively.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-f0b763cbef82402b82ff1a570d10df9a
来源数据集: uspto-grants-1977_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04038412
来源说明: uspto-grants-1977_07

反应 SMILES

[OH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8](=[O:10])[CH3:9].[OH:11][C:12]1[CH:17]=[CH:16][C:15]([C:18](=O)[CH3:19])=[CH:14][CH:13]=1.[OH:21][C:22]1[CH:29]=[CH:28][C:25]([CH:26]=O)=[CH:24][CH:23]=1>>[C:15]1([CH2:18][CH2:19][CH2:22][O:1][C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=2[C:8](=[O:10])[CH3:9])[CH:16]=[CH:17][CH:12]=[CH:13][CH:14]=1.[C:25]1([CH2:26][CH2:13][CH2:12][O:11][C:7]2[CH:2]=[C:3]([C:8](=[O:10])[CH3:9])[CH:4]=[CH:5][CH:6]=2)[CH:28]=[CH:29][CH:22]=[CH:23][CH:24]=1.[C:15]1([CH2:18][CH2:19][CH2:22][O:21][C:6]2[CH:5]=[CH:4][C:3]([C:8](=[O:10])[CH3:9])=[CH:2][CH:7]=2)[CH:16]=[CH:17][CH:12]=[CH:13][CH:14]=1