Potassium Carbonate → HCID 21189140, compound

HRID 2600Notes

Reaction equation

HRID 2600 reaction equation
C([O:4][CH2:5][C:6]1([CH2:28][O:29]C(=O)C)[S:10][C:9]2[CH:11]=[C:12]3[S:16][C:15]([CH2:22][O:23]C(=O)C)([CH2:17][O:18]C(=O)C)[S:14][C:13]3=[CH:27][C:8]=2[S:7]1)(=O)C.C([O-])([O-])=O.[K+].[K+]>CO>[OH:23][CH2:22][C:15]1([CH2:17][OH:18])[S:14][C:13]2[CH:27]=[C:8]3[S:7][C:6]([CH2:5][OH:4])([CH2:28][OH:29])[S:10][C:9]3=[CH:11][C:12]=2[S:16]1

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 18785240HCID 18785240, compound

Product 1

HCID 21189140HCID 21189140, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

2,2,6,6-Tetra(acetoxymethyl)benzo[1,2-d:4,5-d']bis(1,3)dithiole (1.8 g, 3.5 mmol) and K2CO3 (1.9 g) were stirred in methanol (100 mL) for 1 h at ambient temperature. The solvent was evaporated and water (100 mL) was added. The mixture was neutralized (2M HCl) and the precipitate was collected.

Workup

  1. customThe solvent was evaporated
  2. additionwater (100 mL) was added
  3. customthe precipitate was collected

Sources & evidence

ORD record
ord-8a6d6748b1df4808a57a14672a9c86dc
Source dataset
uspto-grants-1998_03
Patent number
US05728370

Reaction notes

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