13801-49-5 → HCID 22401088, compound

HRID 260260Notes

Reaction equation

HRID 260260 reaction equation
[CH:1]1([CH:10]([CH:12]2[C:20]3[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=3)[CH:14]=[CH:13]2)[CH3:11])[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH:3]=[CH:2]1.[CH2:21]([N-:23][CH2:24][CH3:25])[CH3:22].[CH2:26]([N-:28][CH2:29][CH3:30])[CH3:27].[CH2:31]([N-:33][CH2:34][CH3:35])[CH3:32].C([N-]CC)C.[Zr+4:41]>>[CH2:21]([N-:23][CH2:24][CH3:25])[CH3:22].[CH2:26]([N-:28][CH2:29][CH3:30])[CH3:27].[CH2:31]([N-:33][CH2:34][CH3:35])[CH3:32].[Zr+3:41].[CH:12]1([CH:10]([CH:1]2[C:9]3[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=3)[CH:3]=[CH:2]2)[CH3:11])[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=[CH:13]1

Participants

3

Reactant 2

HCID 13960313801-49-5HCID 17763021HCID 17763021, compound

Product 1

HCID 22401088HCID 22401088, compound

Procedure

Bis(indenyl)ethane (0.327 g, 1.27 mmole) were reacted with zirconium tetra(diethyl amide) (1.025 g, 2.70 mmole, 6% excess for 1:2 stoichiometry) at 125° C. for 21/2 hours under nitrogen. This resulted in a light orange-yellow oil: 0.427 g of it were dissolved in 25 ml hexanes (46.1 mmole Zr/ml).

Workup

  1. customThis resulted in a light orange-yellow oil

Sources & evidence

ORD record
ord-7602ed875a734daa958d08691105491a
Source dataset
uspto-grants-1996_06
Patent number
US05527752

Reaction notes

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