(alpha-Chloroethyl)chloroethylmethylsilane → (alpha-Chloroethyl)benzylethylmethylsilane

HRID 260641Notes

Reaction equation

HRID 260641 reaction equation
[Cl:1][CH:2]([SiH:4]([CH2:6][CH2:7]Cl)[CH3:5])[CH3:3].[CH2:9]([Mg]Br)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1>C(OCC)C>[Cl:1][CH:2]([SiH:4]([CH2:6][CH2:7][CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[CH3:5])[CH3:3]

Participants

4

Reactant 2

HCID 123357515(alpha-Chloroethyl)chloroethylmethylsilaneHCID 178419663HCID 178419663, compound

Product 1

HCID 123910545(alpha-Chloroethyl)benzylethylmethylsilane

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To a solution of (α-chloroethyl)chloroethylmethylsilane (0.171 g, 1 mmol) in diethyl ether (5 ml) was added a solution of benzylmagnesium bromide (1 mmol, 1 eq). The mixture was refluxed for 12 hours, then filtered. The product was purified by distillation.

Workup

  1. temperatureThe mixture was refluxed for 12 hours
  2. filtrationfiltered
  3. distillationThe product was purified by distillation

Sources & evidence

ORD record
ord-9027fb34faba4bf8a7bc0a5171441445
Source dataset
uspto-grants-1996_06
Patent number
US05529988

Reaction notes

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