HRID260853

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6993658

未命名化合物

PRODUCTS

生成物

结构：CCCCC(OC/C=C/C(=O)c1cn(CCCC(=O)OCc2ccc(OC)cc2)c2ccccc12)c1ccc(CC(C)C)cc1

HCID86749586

未命名化合物

PROCEDURE

实验过程

The procedure of Ex. 1 was repeated except that (E)-3-[4-[1-(4-isobutylphenyl)pentyloxy]-2-butenoyl]indole obtained in Step 4 of Pre. Ex. 19 was used in place of 3-heptanoylindole, and 4-methoxybenzyl 4-bromobutyrate obtained in Step 5 of Pre. Ex. 19 was used in place of 4-bromobutyrate to give 4-methoxybenzyl (E)-4-[3-[4-[1-(4-isobutylphenyl)pentyloxy]-2-butenoyl]1-indolyl]butyrate as an oil.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8f199d4c2ddc47aeae693f74e8f60d27
来源数据集: uspto-grants-1996_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05530019
来源说明: uspto-grants-1996_06

反应 SMILES

[CH2:1]([C:5]1[CH:10]=[CH:9][C:8]([CH:11]([O:16][CH2:17]/[CH:18]=[CH:19]/[C:20]([C:22]2[C:30]3[C:25](=[CH:26][CH:27]=[CH:28][CH:29]=3)[NH:24][CH:23]=2)=[O:21])[CH2:12][CH2:13][CH2:14][CH3:15])=[CH:7][CH:6]=1)[CH:2]([CH3:4])[CH3:3].C(C1C2C(=CC=CC=2)NC=1)(=O)CCCCCC.Br[CH2:49][CH2:50][CH2:51][C:52]([O:54][CH2:55][C:56]1[CH:61]=[CH:60][C:59]([O:62][CH3:63])=[CH:58][CH:57]=1)=[O:53].BrCCCC([O-])=O>>[CH2:1]([C:5]1[CH:6]=[CH:7][C:8]([CH:11]([O:16][CH2:17]/[CH:18]=[CH:19]/[C:20]([C:22]2[C:30]3[C:25](=[CH:26][CH:27]=[CH:28][CH:29]=3)[N:24]([CH2:49][CH2:50][CH2:51][C:52]([O:54][CH2:55][C:56]3[CH:61]=[CH:60][C:59]([O:62][CH3:63])=[CH:58][CH:57]=3)=[O:53])[CH:23]=2)=[O:21])[CH2:12][CH2:13][CH2:14][CH3:15])=[CH:9][CH:10]=1)[CH:2]([CH3:4])[CH3:3]