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Thionyl Chloride → 2-Methoxy-10,11-dihydrodibenzo[b,f]thiepin-9-carbonyl chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 反応物 | Dibenzo(b,f)thiepin-1-carboxylic acid, 10,11-dihydro-8-methoxy- | HCID 3045903 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | 2-Methoxy-10,11-dihydrodibenzo[b,f]thiepin-9-carbonyl chloride | HCID 23337065 | — |
反応手順
An amount of 575 mg of 2-methoxy-9-carboxy-10,11-dihydrodibenzo[b,f]thiepin was dissolved in 10 ml of anhydrous benzene and to the mixture was added 1 ml of thionyl chloride. The resulting mixture was refluxed for 3 hours and freed of solvent under reduced pressure to obtain 614 mg of 2-methoxy-10,11-dihydrodibenzo[b,f]thiepin-9-carbonyl chloride.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04166127 |
| 出典データセット | uspto-grants-1979_08 |
| ORD ID | ord-477cfffb6a9447d6a8a2c07314a01440 |
| 出典メモ | uspto-grants-1979_08 |