Dimethylamine → alpha-(Nitromethyl)benzyl dimethyldithiocarbamate

HRID 26156Notes

Reaction equation

HRID 26156 reaction equation
[CH3:1][NH:2][CH3:3].[C:4](=[S:6])=[S:5].[N+:7]([CH:10]=[CH:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)([O-:9])=[O:8]>CO>[CH3:1][N:2]([CH3:3])[C:4](=[S:6])[S:5][CH:11]([CH2:10][N+:7]([O-:9])=[O:8])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1

Participants

5

Reactant 3

HCID 674DimethylamineHCID 6348Carbon DisulfideHCID 7626Beta-Nitrostyrene

Product 1

HCID 21324598alpha-(Nitromethyl)benzyl dimethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Similarly, gradual addition of dimethylamine (45.1 grame, 1 mole) to a methanol solution of carbon disulfide (83.6 grams, 1.1 mole) and β-nitrostyrene (149.1 grams, 1 mole) at 10° C.-30° C. yields α-(nitromethyl)benzyl dimethyldithiocarbamate.

Sources & evidence

ORD record
ord-98e2088458ec45f49bdde01b01fe530b
Source dataset
uspto-grants-1979_04
Patent number
US04148795

Reaction notes

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