Ethanol → HCID 20285880, compound

HRID 26168Notes

Reaction equation

HRID 26168 reaction equation
[N+:1]([C:4]1[CH:5]=[CH:6][CH:7]=[C:8]2[C:13]=1[C:12]([C:14]([OH:16])=[O:15])=[CH:11][CH:10]=[C:9]2[C:17]([OH:19])=[O:18])([O-:3])=[O:2].[CH2:20](O)[CH3:21]>Cl>[CH2:20]([O:18][C:17]([C:9]1[C:8]2[C:13](=[C:4]([N+:1]([O-:3])=[O:2])[CH:5]=[CH:6][CH:7]=2)[C:12]([C:14]([OH:16])=[O:15])=[CH:11][CH:10]=1)=[O:19])[CH3:21]

Participants

4

Reactant 2

HCID 702EthanolHCID 13545960HCID 13545960, compound

Product 1

HCID 20285880HCID 20285880, compound

Reagents, catalysts & solvents 1

HCID 313Hydrochloric AcidSolvent

Procedure

52 parts of 8-nitro-naphthalene-1,4-dicarboxylic acid are dissolved in 700 parts of absolute ethyl alcohol and the solution is boiled under reflux for 12 hours whilst continuously passing in hydrogen chloride gas. The resulting solution is evaporated in vacuo. The 4-ethoxycarbonyl-8-nitro-naphthalene-1-carboxylic acid of the formula ##STR15## which is obtained in this way, melts at 178° to 180°.

Workup

  1. temperatureunder reflux for 12 hours
  2. customThe resulting solution is evaporated in vacuo

Sources & evidence

ORD record
ord-33e9e2f40abb460a94610133ef3c3aaf
Source dataset
uspto-grants-1979_04
Patent number
US04148805

Reaction notes

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